Ji Zhang 12/12/1998 Period 1 Chem Lab: Molar Volume of a Gas Objectives: The objectives of this lab are to determine an experimental molar volume for hydrogen; to study mass-volume relationships in chemical reactions; and to become familiar with the relationship between the density and molecular mass of a gas. Data: 1 length of Mg ribbon 4.00cm 2 mass of 1 cm Mg ribbon .0116g 3 mass of Mg ribbon used .0464g 4 moles of Mg ribbon used .00191m 5 volume of H gas collected 46mL 6 temp. of water and of gas 25C 7 barometric pressure 775mm 8 vapor pressure of water 23.8mm *9 pressure of dry hydrogen gas 751.2mm *10 volume in liters of hydrogen gas 41.65mL (corrected to STP) 11 moles of hydrogen gas (equal .00191m to moles of Mg) 12 molar volume (liters/1mole) 21806 l/m 13 theoretical molar volume for 22400 l/m perfect gas 14 percentage deviation of exp. 97.35% and theo. Value calculation s *9 barometric pressure- vapor pressure of H2O= pressure of dry hydrogen gas 775mm - 23.8mm= 751.2mm *10 PV/T = PV/T 751.2t*45mL 760t * XmL ---------------- = -------------- -- 298K 273K (this is STP) X= 41.65mL (by cross multiplication) Sketch of experiment: please see next page Conclusion question: sources of error There were various possible sources of error in this experiment. If air was let in the gas tube during or before the magnesium reaction, then the volume of the gas inside the tube will be too big. If the magnesium did not completely react with the hydrochloric acid, then not enough gas will be produced and the volume of the gas produced will be too small. Magnesium may not react completely due to various reasons. For example, it may not be 100% pure.